The Ghana Education Service (GES) has interdicted the headmaster of Fijai Senior High School, Mr Kenneth Agbomadze with immediate effect.
Mr Agbomadze has been accused of charging illegal fees in the school.
The allegation is being investigated.
Mr Agbomadze has been ordered to hand over the administration of the school to the Western Regional Director of Education.
An investigative committee has been given two weeks to submit its report to management.